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Brown-Driver-Briggs Abridged Hebrew Lexicon
רֹאשׁ and רוֹשׁn.m. a bitter and poisonous herb, then venom
Strong Concise Dictionary Of The Words In The Hebrew Bible
H7219רֹאשׁrôʼsh; or רוֹשׁ; (Deuteronomy 32:32), apparently the same as 7218; a poisonous plant, probably the poppy (from its conspicuous head); generally poison (even of serpents) — gall, hemlock, poison, venom.